Tetrahedral chalcogenide clusters and open frameworks

被引：232

作者：

Bu, XH

Zheng, NF

Feng, PY

机构：

[1] Calif State Univ Long Beach, Dept Chem & Biochem, Long Beach, CA 90840 USA

[2] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2004年 / 10卷 / 14期

关键词：

chalcogens; cluster compounds; conducting materials; microporous materials; supertetrahedral clusters; transition metals; zeolites;

D O I：

10.1002/chem.200306041

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By integrating porosity with electrical or optical properties, microporous chalcogenides may have unique applications. Here we review recent advances and discuss concepts in the synthesis and crystal structure of tetrahedral clusters and their frameworks. These chalcogenides can be viewed as trivalent metal chalcogenides doped with tetra-, di-, or monovalent metal cations. Low-valent cations help to increase the cluster size, while high-valent cations have the opposite effect.

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收藏

页码：3356 / 3362

页数：7

相关论文

共 40 条

[1] Modular assembly and phase study of two- and three-dimensional porous tin(IV) selenides [J].

Ahari, H ;

Lough, A ;

Petrov, S ;

Ozin, GA ;

Bedard, RL .

JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (06) :1263-1274

[2]

BEDARD RL, 1989, STUD SURF SCI CATAL, V49, P375

[3]

Bu X., 2004, ANGEW CHEM, V116, P1528

[4] Three-dimensional frameworks of gallium selenide supertetrahedral clusters [J].

Bu, XH ;

Zheng, NF ;

Wang, XQ ;

Wang, B ;

Feng, PY .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (12) :1502-1505

[5] Templated assembly of sulfide nanoclusters into Cubic-C3N4 type framework [J].

Bu, XH ;

Zheng, NF ;

Li, YQ ;

Feng, PY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (20) :6024-6025

[6] Pushing up the size limit of chalcogenide supertetrahedral clusters:: Two- and three-dimensional photoluminescent open frameworks from (Cu5In30S54)13- clusters [J].

Bu, XH ;

Zheng, NF ;

Li, YQ ;

Feng, PY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (43) :12646-12647

[7] On the formation of framework indium sulfides [J].

Cahill, CL ;

Parise, JB .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (09) :1475-1482

[8] A novel 3-dimensional open framework sulfide based upon the [In10S20]10- supertetrahedron:: DMA-InS-SB1 [J].

Cahill, CL ;

Ko, YH ;

Parise, JB .

CHEMISTRY OF MATERIALS, 1998, 10 (01) :19-21

[9] Synthesis and structure of MnGe4S10 center dot(C6H14N2)center dot 3H2O: A novel sulfide framework analogous to zeolite Li-A(BW) [J].

Cahill, CL ;

Parise, JB .

CHEMISTRY OF MATERIALS, 1997, 9 (03) :807-811

[10]

Cheetham A. K., 1999, ANGEW CHEM, V111, P3466

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