Solid-liquid equilibria for different heptanones with benzene, cyclohexane, and ethanol

被引：29

作者：

Fiege, C ^{[1
]}

Joh, R ^{[1
]}

Petri, M ^{[1
]}

Gmehling, J ^{[1
]}

机构：

[1] CARL VON OSSIETZKY UNIV, LEHRSTUHL TECH CHEM FB9, D-26111 OLDENBURG, GERMANY

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1996年 / 41卷 / 06期

关键词：

D O I：

10.1021/je960140h

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The liquidus lines of solid-liquid equilibria for the binary systems 2-heptanone, 3-heptanone, and 4-heptanone with benzene, cyclohexane, and ethanol were determined by means of the visual method. Furthermore enthalpies of fusion of the isomeric heptanones were measured with a Tian-Calvet calorimeter. The experimental SLE data were compared with those calculated from the modified UNIFAC (Dortmund) group contribution method.

引用

页码：1431 / 1433

页数：3

共 8 条

[1] [Anonymous], 1963, RECENT PROGR MICROCA
[2] FROM UNIFAC TO MODIFIED UNIFAC TO PSRK WITH THE HELP OF DDB
GMEHLING, J
[J]. FLUID PHASE EQUILIBRIA, 1995, 107 (01) : 1 - 29
[3] A MODIFIED UNIFAC MODEL .2. PRESENT PARAMETER MATRIX AND RESULTS FOR DIFFERENT THERMODYNAMIC PROPERTIES
GMEHLING, J
LI, JD
SCHILLER, M
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1993, 32 (01) : 178 - 193
[4] A DATA-BANK FOR AZEOTROPIC DATA - STATUS AND APPLICATIONS
GMEHLING, J
MENKE, J
KRAFCZYK, J
FISCHER, K
[J]. FLUID PHASE EQUILIBRIA, 1995, 103 (01) : 51 - 76
[5] Gmehling J., 1992, Thermodynamik, Vsecond
[6] GMEHLING J, 1994, COMMUNICATION
[7] SOLID-LIQUID EQUILIBRIA IN BINARY-MIXTURES OF ORGANIC-COMPOUNDS
JAKOB, A
JOH, R
ROSE, C
GMEHLING, J
[J]. FLUID PHASE EQUILIBRIA, 1995, 113 (1-2) : 117 - 126
[8] WYNN NP, 1992, CHEM ENG PROG, V88, P52

← 1 →