Photogeneration of heptacene in a polymer matrix

被引：226

作者：

Mondal, Rajib ^{[1
]}

Shah, Bipin K. ^{[1
]}

Neckers, Douglas C. ^{[1
]}

机构：

[1] Bowling Green State Univ, Ctr Photochem Sci, Bowling Green, OH 43403 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 30期

关键词：

GROUND-STATES; DERIVATIVES; PENTACENE; ELECTRONICS; REACTIVITY; POLYACENE; HEXACENE; ACENES;

D O I：

10.1021/ja063823i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Heptacene (1) was generated by the photodecarbonylation of 7,16-dihydro-7,16-ethanoheptacene-19,20-dione (2) in a polymer matrix using a UV-LED lamp (395 ± 25 nm). Compound 1 showed a long wavelength absorption band extending from 600 to 825 nm (λmax ∼760 nm) and was found to be stable up to 4 h in the polymer matrix. However, irradiation of a solution of 2 in toluene produced only oxygen adducts. Copyright © 2006 American Chemical Society.

引用

页码：9612 / 9613

页数：2

共 28 条

[1]

[Anonymous], 1997, POLYCYCLIC AROMATIC, DOI DOI 10.1021/jo0104577

[2]

[Anonymous], 1986, THESIS U CALIFORNIA

[3] CYCLIC DIENES .11. NEW SYNTHESES OF HEXACENE AND HEPTACENE [J].

BAILEY, WJ ;

LIAO, CW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1955, 77 (04) :992-993

[4] Tetrathiafulvalenes, oligoacenenes, and their buckminsterfullerene derivatives: The brick and mortar of organic electronics [J].

Bendikov, M ;

Wudl, F ;

Perepichka, DF .

CHEMICAL REVIEWS, 2004, 104 (11) :4891-4945

[5] Oligoacenes: Theoretical prediction of open-shell singlet diradical ground states [J].

Bendikov, M ;

Duong, HM ;

Starkey, K ;

Houk, KN ;

Carter, EA ;

Wudl, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (24) :7416-7417

[6] 4 HIGHER ANNELLATED PYRENES WITH ACENE CHARACTER [J].

BOGGIANO, B ;

CLAR, E .

JOURNAL OF THE CHEMICAL SOCIETY, 1957, (JUN) :2681-2689

[7] A reiterative approach to 2,3-disubstituted naphthalenes and anthracenes [J].

Bowles, DM ;

Anthony, JE .

ORGANIC LETTERS, 2000, 2 (01) :85-87

[8] Heptacene, a simple "ultragreen" hydrocarbon (aromatic hydrocarbons, XXXV. Announcement). [J].

Clar, E .

BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1942, 75 :1330-1338

[9]

Clar E., 1964, POLYCYCLIC HYDROCARB, VI

[10]

*CTR PHOT SCI, 581 CTR PHOT SCI

← 1 2 3 →