Cyano-bridged coordination polymer nanoparticles

被引：67

作者：

Larionova, Joulia ^{[1
]}

Guari, Yannick ^{[1
]}

Sangregorio, Claudio ^{[2
]}

Guerina, Christian ^{[1
]}

机构：

[1] Univ Montpellier 2, CNRS, ENSCM, UM1,Inst Charles Gerhardt Montpellier,UMR 5253, F-34095 Montpellier 5, France

[2] Univ Florence, Dipartimento Chim, Res Unit, INSTM, I-50019 Sesto Fno Firenze, Italy

来源：

NEW JOURNAL OF CHEMISTRY | 2009年 / 33卷 / 06期

关键词：

PRUSSIAN BLUE NANOPARTICLES; TRANSITION-METAL NANOPARTICLES; MAGNETIC-ORDERING TEMPERATURE; MOLECULAR-BASED MAGNETS; IN-SITU FORMATION; IONIC LIQUIDS; GOLD NANOPARTICLES; SPIN-GLASS; BILAYER-MEMBRANES; THIN-FILM;

D O I：

10.1039/b900918c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A survey on the synthesis of cyano-bridged coordination polymer nanoparticles (CPNs) performed in our group and on the study of their related magnetic properties is given. Two synthetic approaches consisting in the one-pot synthesis of soluble CPNs and in the sequential growth of CPNs onto appropriate matrices are reviewed. A special emphasis is placed on the magnetic properties of CPNs and the determination of the magnetic regime in these systems, which strongly depends on various factors. We show that the size of the nanoparticles, the magnetostatic interparticles and/or the NP-matrix interactions provide significant modification of the superparamagnetic relaxation regime.

引用

页码：1177 / 1190

页数：14

共 127 条

[1] Metal(II) hexacyanochromate(III) MCr (M = Co, Cu, Fe) coordination nanoparticles stabilized by alkyl surface coordination ligand: Downsizing effect on their crystal structure and magnetic properties [J].