Amorphous fluoropolymers from tetrafluoroethylene and bulky vinyl esters or vinyl ethers

被引：5

作者：

Feiring, AE ^{[1
]}

Wonchoba, ER ^{[1
]}

Fischel, BE ^{[1
]}

Thieu, TV ^{[1
]}

Nassirpour, MR ^{[1
]}

机构：

[1] DuPont Co Inc, Cent Res & Dev, Expt Stn, Wilmington, DE 19880 USA

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2002年 / 118卷 / 1-2期

关键词：

amorphous fluoropolymers; tetrafluoroethylene copolymers; vinyl ester copolymers; vinyl ether copolymers;

D O I：

10.1016/S0022-1139(02)00205-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Copolymers of tetrafluoroethylene (TFE) with vinyl esters and vinyl ethers having adamantyl or norbornyl side chains are prepared in good yield by radical polymerizations in organic solvents. The polymers are thermally stable, soluble in standard organic solvents and can have glass transition temperatures more than 100 degreesC higher than the corresponding copolymers with linear aliphatic side chains. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：95 / 98

页数：4

共 14 条

[1] Evaluation of the spacer effect on adamantane-containing vinyl polymer Tg's [J].

Acar, HY ;

Jensen, JJ ;

Thigpen, K ;

McGowen, JA ;

Mathias, LJ .

MACROMOLECULES, 2000, 33 (10) :3855-3859

[2]

[Anonymous], ORGANOFLUORINE CHEM

[3]

FEIRING AE, Patent No. 2000017712

[4] RADIATION-INDUCED COPOLYMERIZATION OF TETRAFLUOROETHYLENE WITH VINYL ETHERS [J].

HIKITA, T ;

TABATA, Y ;

OSHIMA, K ;

ISHIGURE, K .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1972, 10 (10) :2941-2949

[5]

HIKITA T, 1977, MACROMOL SYNTHESES, V6, P15

[6] RADICAL POLYMERIZATION OF ENDO- OR EXO-VINYL BICYCLO[2.2.1]-HEPTANE-2-CARBOXYLATE [J].

IMOTO, M ;

FUKUDA, W ;

OTSU, T .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER LETTERS, 1963, 1 (05) :225-&

[7]

JORDAN RF, 1993, Patent No. 5214173

[8] Synthesis of linear poly(tetrafluoroethylene-co-vinyl acetate) in carbon dioxide [J].

Lousenberg, RD ;

Shoichet, MS .

MACROMOLECULES, 2000, 33 (05) :1682-1685

[9] SYNTHESIS AND CHARACTERIZATION OF POLY(1-ADAMANTYL METHACRYLATE) - EFFECTS OF THE ADAMANTYL GROUP ON RADICAL POLYMERIZATION KINETICS AND THERMAL-PROPERTIES OF THE POLYMER [J].

MATSUMOTO, A ;

TANAKA, S ;

OTSU, T .

MACROMOLECULES, 1991, 24 (14) :4017-4024

[10] SYNTHESIS AND POLYMERIZATION OF VINYL ESTERS AND VINYL ETHERS HAVING BULKY SUBSTITUENTS [J].

NOZAKURA, SI ;

OKAMOTO, T ;

TOYORA, K ;

MURAHASH.S .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1973, 11 (05) :1043-1051

← 1 2 →