Ionic liquids:: First direct determination of their cohesive energy

被引：283

作者：

Santos, Luis M. N. B. F.

Lopes, Jose N. Canongia ^{[1
]}

Coutinho, Joao A. P.

Esperanca, Jose M. S. S.

Gomes, Ligia R.

Marrucho, Isabel M.

Rebelo, Luis P. N.

机构：

[1] Inst Super Tecn, Ctr Quim Estrutural, P-1049001 Lisbon, Portugal

[2] Univ Porto, Ctr Invest Quim, Fac Ciencias, P-4169007 Oporto, Portugal

[3] Univ Nova Lisboa, Inst Tecnol Quim & Biol, P-2780901 Oeiras, Portugal

[4] Univ Aveiro, CICECO, P-3810193 Aveiro, Portugal

[5] Univ Fernando Pessoa, CBFC, Fac Ciencias Saude, P-4200150 Oporto, Portugal

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 02期

关键词：

D O I：

10.1021/ja067427b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molar enthalpies of vaporization, delta H-g(1)m(0)(T), of a homologous series of 1-alkyl-3-methylimidazolium bis(trifluoromethyl sulfonyl)imides, [C(n)mim][NTf2], (with 2 <= n <= 8) were directly determined for the first time. The results obtained in this study emphasize and constitute clear experimental support for the novel concept that these liquid salts are composed of polar and nonpolar domains; that is, they exhibit microphase segregation.

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页码：284 / 285

页数：2

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