Undulated Multicompartment Cylinders by the Controlled and Directed Stacking of Polymer Micelles with a Compartmentalized Corona

被引：116

作者：

Fang, Bing ^{[1
]}

Walther, Andreas ^{[1
]}

Wolf, Andrea ^{[1
]}

Xu, Youyong ^{[1
]}

Yuan, Jiayin ^{[1
]}

Mueller, Axel H. E. ^{[1
]}

机构：

[1] Univ Bayreuth, Bayreuther Zentrum Kolloide & Grenzflachen, D-95440 Bayreuth, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 16期

关键词：

aggregation; block terpolymers; micelles; self-assembly; solvent effects; ABC TRIBLOCK COPOLYMER; AMPHIPHILIC BLOCK-COPOLYMERS; MULTIPLE MORPHOLOGIES; WORMLIKE MICELLES; JANUS MICELLES; SEGREGATION; DIBLOCK; POLAR;

D O I：

10.1002/anie.200806051

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Like a bamboo rod: Long, bamboo-like undulated cylinders with distinct branch points and end groups (see picture) were obtained by the stacking of block terpolymer micelles that contain a fluorinated polybutadiene core and a compartmentalized corona of poly(4-tert-butoxystyrene) and poly(tert-butyl methacrylate). Stacking of the polymer micelles, which can be reversed, occurred when the solvent was changed from dioxane to ethanol. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2877 / 2880

页数：4

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