Ligand trans-effect:: using an old concept as a novel approach to bis(dipolar) NLO-phores

被引:64
作者
Fave, C
Hissler, M
Sénéchal, K
Ledoux, I
Zyss, J
Réau, R
机构
[1] Univ Rennes 1, UMR 6509, Inst Chim, CNRS, F-35042 Rennes, France
[2] ENS Cachan, Lab Phys Quant Mol, F-94235 Cachan, France
关键词
D O I
10.1039/b203149c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In plane parallel arrangement and enhancement of NLO-activity are observed upon coordination of heteroditopic dipoles containing a phosphole ring on square-planar d(8)-palladium centre.
引用
收藏
页码:1674 / 1675
页数:2
相关论文
共 41 条
  • [1] Large molecular hyperpolarizabilities. Quantitative analysis of aromaticity and auxiliary donor-acceptor effects
    Albert, IDL
    Marks, TJ
    Ratner, MA
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (28) : 6575 - 6582
  • [2] [Anonymous], COMPREHENSIVE HETERO
  • [3] Braunstein P, 2001, ANGEW CHEM INT EDIT, V40, P680, DOI 10.1002/1521-3773(20010216)40:4<680::AID-ANIE6800>3.0.CO
  • [4] 2-0
  • [5] Braunstein P, 2000, ANGEW CHEM INT EDIT, V39, P2867, DOI 10.1002/1521-3773(20000818)39:16<2867::AID-ANIE2867>3.0.CO
  • [6] 2-X
  • [7] Synthesis and second-order nonlinear optical properties of new palladium(II) and platinum(II) Schiff-base complexes
    Buey, J
    Coco, S
    Diez, L
    Espinet, P
    Martin-Alvarez, JM
    Miguel, JA
    Garcia-Granda, S
    Tesouro, A
    Ledoux, I
    Zyss, J
    [J]. ORGANOMETALLICS, 1998, 17 (09) : 1750 - 1755
  • [8] A comparison of the pentaammine(pyridyl)ruthenium(II) and 4-(dimethylamino)phenyl groups as electron donors for quadratic non-linear optics
    Coe, BJ
    Harris, JA
    Clays, K
    Persoons, A
    Wostyn, K
    Brunschwig, BS
    [J]. CHEMICAL COMMUNICATIONS, 2001, (17) : 1548 - 1549
  • [9] Theoretical study of the structure-property relationship in phosphole monomers
    Delaere, D
    Dransfeld, A
    Nguyen, MT
    Vanquickenborne, LG
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (09) : 2631 - 2636
  • [10] Novel chiral bis-dipolar 6,6'-disubstituted binaphthol derivatives for second-order nonlinear optics. Synthesis and linear and nonlinear optical properties
    Deussen, HJ
    Hendrickx, E
    Boutton, C
    Krog, D
    Clays, K
    Bechgaard, K
    Persoons, A
    Bjornholm, T
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (29) : 6841 - 6852