Stable macrocyclic and tethered donor-acceptor systems. Intramolecular bipyridinium and tetrathiafulvalene assemblies

被引：57

作者：

Simonsen, KB

Zong, KW

Rogers, RD

Cava, MP

Becher, J

机构：

[1] UNIV ALABAMA,DEPT CHEM,TUSCALOOSA,AL 35487

[2] ODENSE UNIV,DEPT CHEM,DK-5230 ODENSE M,DENMARK

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1997年 / 62卷 / 03期

关键词：

D O I：

10.1021/jo961782a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of compounds has been prepared in which a tetrathiafulvalene (TTF)-derived donor is covalently tethered or bridged to one or more bipyridinium (viologen) accepters. The relative degree of charge transfer observed in this series is discussed as a function of structure. The greatest CT effect is seen in the cyclophanes 9a-c and 13.

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页码：679 / 686

页数：8

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