Preparation of asymmetrical functionalized TTF; Characterization of their charge transfer salts.

被引:18
作者
Binet, L
Montginoul, C
Fabre, JM
Ouahab, L
Golhen, S
Becher, J
机构
[1] UNIV RENNES 1,CHIM SOLIDE & INORGAN MOL LAB,URA 1495,F-35042 RENNES,FRANCE
[2] ODENSE UNIV,DEPT CHEM,DK-5230 ODENSE,DENMARK
关键词
heterocycle synthesis; coupling reactions; electrocrystallisation; conductivity organic conductors based on radical cation;
D O I
10.1016/S0379-6779(97)80922-8
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Introduction of cyanoethyl groups (-(CH2)(2)-CN) on appropriate precursors allowed us to easily synthesize two new series of functionalized TTFs [1, 2]. Their radical cation salts and charge transfer complexes have been prepared and their electrical properties have been studied. A few crystal structures have been determined.
引用
收藏
页码:1825 / 1826
页数:2
相关论文
共 2 条
[1]   Preparation and chemistry of new unsymmetrically substituted tetrachalcogenofulvalenes bearing CN(CH2)(2)X and HO(CH2)(2)X groups (X=S or Se) [J].
Binet, L ;
Fabre, JM ;
Montginoul, C ;
Simonsen, KB ;
Becher, J .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1996, (08) :783-788
[2]  
SVENSTRUP N, 1984, SYNTHESIS-STUTTGART, P809