Electrochemical properties of novel ionic liquids for electric double layer capacitor applications

被引：693

作者：

Sato, T ^{[1
]}

Masuda, G ^{[1
]}

Takagi, K ^{[1
]}

机构：

[1] Nisshinbo Ind Inc, Ctr Res & Dev, Midori Ku, Chiba 2670056, Japan

来源：

ELECTROCHIMICA ACTA | 2004年 / 49卷 / 21期

关键词：

ionic liquids; aliphatic quaternary ammonium salt; electric double layer capacitor; specific conductivity; specific capacitance;

D O I：

10.1016/j.electacta.2004.03.030

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

An aliphatic quaternary ammonium salt which has a methoxyethyl group on the nitrogen atom formed an ionic liquid (room temperature molten salt) when combined with the tetrafluoroborate (BF4-) and bis(trifluoromethylsulfonyl)imide [TFSI; (CF3SO2)(2)N-] anions. The limiting oxidation and reduction potentials, specific conductivity, and some other physicochemical properties of the novel ionic liquids, N,N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium tetrafluoroborate (DEME-BF4) and DEME-TFSI have been evaluated and compared with those of 1-ethyl-3-methylimidazolium tetrafluoroborate. DEME-BF4 is a practically useful ionic liquid for electrochemical capacitors as it has a quite wide potential window (6.0 V) and high ionic conductivity (4.8 mS cm(-1) at 25 degreesC). We prepared an electric double layer capacitor (EDLC) composed of a pair of activated carbon electrodes and DEME-BF4 as the electrolyte. This EDLC (working voltage similar to2.5 V) has both, a higher capacity above room temperature and a better charge-discharge cycle durability at 100 degreesC when compared to a conventional EDLC using an organic liquid electrolyte such as a tetraethylammonium tetrafluoroborate in propylene carbonate. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：3603 / 3611

页数：9

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