High temperature-induced high enantioselectivity of lipase for esterifications of 2-phenoxypropionic acids in organic solvent

被引:23
作者
Yasufuku, Y
Ueji, S
机构
[1] KOBE UNIV,FAC HUMAN DEV & SCI,DIV NAT ENVIRONM & BIOORG CHEM,NADA KU,KOBE,HYOGO 657,JAPAN
[2] KOBE UNIV,FAC HUMAN DEV & SCI,GRAD SCH SCI & TECHNOL,NADA KU,KOBE,HYOGO 657,JAPAN
关键词
D O I
10.1006/bioo.1997.1056
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The improved enantioselectivities were observed for lipase MY-catalyzed esterifications of 2-phenoxypropionic acids in organic solvent at high reaction temperature. In this paper, we proposed an assumed model for explaining its high temperature-induced high enantioselectivity. (C) 1997 Academic Press.
引用
收藏
页码:88 / 99
页数:12
相关论文
共 19 条
[1]   GENERAL-ASPECTS AND OPTIMIZATION OF ENANTIOSELECTIVE BIOCATALYSIS IN ORGANIC-SOLVENTS - THE USE OF LIPASES [J].
CHEN, CS ;
SIH, CJ .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (06) :695-707
[2]   QUANTITATIVE-ANALYSES OF BIOCHEMICAL KINETIC RESOLUTIONS OF ENANTIOMERS [J].
CHEN, CS ;
FUJIMOTO, Y ;
GIRDAUKAS, G ;
SIH, CJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (25) :7294-7299
[3]   ENZYMATIC CATALYSIS IN MONOPHASIC ORGANIC-SOLVENTS [J].
DORDICK, JS .
ENZYME AND MICROBIAL TECHNOLOGY, 1989, 11 (04) :194-211
[4]   HOW CAN THE SOLVENT AFFECT ENZYME ENANTIOSELECTIVITY [J].
FITZPATRICK, PA ;
KLIBANOV, AM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (08) :3166-3171
[5]   EFFECTS OF WATER AND WATER-MIMICKING SOLVENTS ON THE LIPASE-CATALYZED ESTERIFICATION IN AN APOLAR SOLVENT [J].
KITAGUCHI, H ;
ITOH, I ;
ONO, M .
CHEMISTRY LETTERS, 1990, (07) :1203-1206
[6]  
KLIBANOV A M, 1986, Chemtech, V16, P354
[7]   ASYMMETRIC TRANSFORMATIONS CATALYZED BY ENZYMES IN ORGANIC-SOLVENTS [J].
KLIBANOV, AM .
ACCOUNTS OF CHEMICAL RESEARCH, 1990, 23 (04) :114-120
[8]   SUBSTRATE STRUCTURE AND SOLVENT HYDROPHOBICITY CONTROL LIPASE CATALYSIS AND ENANTIOSELECTIVITY IN ORGANIC MEDIA [J].
PARIDA, S ;
DORDICK, JS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (06) :2253-2259
[9]   REACTION OF 1-BROMO-2,3-EPOXYBUTANE AND 3-BROMO-1,2-EPOXYBUTANE WITH PHENOL [J].
ROWTON, RL ;
RUSSELL, RR .
JOURNAL OF ORGANIC CHEMISTRY, 1958, 23 (07) :1057-1058
[10]   INDUCED-FIT MOVEMENTS IN ADENYLATE KINASES [J].
SCHULZ, GE .
FARADAY DISCUSSIONS, 1992, 93 :85-93