Kinetics of the gas-liquid reaction between carbon dioxide and hydroxide ions

被引：87

作者：

Kucka, L ^{[1
]}

Kenig, EY ^{[1
]}

Górak, A ^{[1
]}

机构：

[1] Univ Dortmund, Dept Chem Engn, D-44221 Dortmund, Germany

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2002年 / 41卷 / 24期

关键词：

D O I：

10.1021/ie020452f

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Gas-liquid reaction kinetics of the reactions between carbon dioxide and hydroxide ions is obtained via dynamic experiments in a stirred cell reactor. The evaluation of experiments is performed using a new technique enabling experimental series without time-consuming solvent purification after each experiment. A new expression for the reaction rate constant at infinite dilution is obtained. Furthermore, a kinetic description of aqueous potassium hydroxide and aqueous sodium hydroxide solutions in the temperature range between 20 and 50 degreesC is proposed.

引用

页码：5952 / 5957

页数：6

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2-O

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