Inhibition of copper corrosion in HCI 0.5 M medium by some triazolic compounds

被引:38
作者
EL Issami, S
Bazzi, L
Hilali, M
Salghi, R
Kertit, S
机构
[1] Fac Sci, Lab Chim Phys, Dagadir, Morocco
[2] Lab Estab Autonome Control & Coordinat Exportat D, Dagadir, Morocco
[3] Ecole Normale Super Takaddoum, Lab Phys Chim Mat, Rabat, Morocco
来源
ANNALES DE CHIMIE-SCIENCE DES MATERIAUX | 2002年 / 27卷 / 04期
关键词
D O I
10.1016/S0151-9107(02)80019-8
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Inhibition of copper corrosion in HCl 0.5 M medium by some. triazolic compounds. Some triazole-type organic compounds were tested as corrosion inhibitors for copper in 0.5 M HCl solution at 20degreesC. Electrochemical (potentiodynamic polarization and polarization resistance measurements) and gravimetric methods were used for this study. The obtained results showed that 3-amino-1,2,4 triazole (ATA) and 3,5 diamino-1,2,4 triazole (DTA) effectively reduce the corrosion rate of copper. The inhibition efficiency (E%) of these compounds increases with their concentrations and attains maximum values at 10(-3)M and 10(-4)M for ATA and DTA, respectively. The variation of efficiency with logC shows that these inhibitors are adsorbed on the metallic surface according to the Frumkin adsorption isotherm model.
引用
收藏
页码:63 / 72
页数:10
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