Correlated proton affinities of arylphosphines

被引：7

作者：

Howard, ST

Foreman, JP

Edwards, PG

机构：

[1] Department of Chemistry, University of Wales, Cardiff

来源：

CHEMICAL PHYSICS LETTERS | 1997年 / 264卷 / 3-4期

关键词：

D O I：

10.1016/S0009-2614(96)01353-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Theoretical gas phase proton affinities are presented at the MP2 level for phenylphosphine, dimethylphenylphosphine and the bicyclic phosphines phenylphosphabicyclo(3,3,I)nonane and 1H,5H-benzo(ii)-5-phosphadecalin, The latter two species have proton affinities larger than triphenylphosphine.

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页码：454 / 458

页数：5

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