Metal chelates with salicylidene-3-carboethoxy-4,5-dimethylthiophene derivatives as azomethine ligands of a new type

被引：8

作者：

Burlov, A. S.

Shepelenko, E. N.

Vasil'chenko, I. S.

Antsyshkina, A. S.

Sadikov, G. G.

Matuev, P. V.

Nikolaevskii, S. A.

Borodkin, G. S.

Sergienko, V. S.

Bren, V. A.

Garnovskii, A. D.

机构：

[1] Rostov State Univ, Inst Phys & Organ Chem, Rostov Na Donu 344104, Russia

[2] Russian Acad Sci, S Sci Ctr, Rostov Na Donu, Russia

[3] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2006年 / 32卷 / 12期

关键词：

D O I：

10.1134/S1070328406120049

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学]; 081704 [应用化学];

摘要：

New azomethine derivatives of salicylidene-3-carboethoxy-4,5-dimethylthiophene and their metal chelates are synthesized. The enolimine tautomeric form of the azomethine system of the ligand is determined from the data of H-1 NMR and IR spectroscopy. According to the IR spectral data, the structures of the Co, Ni, Cu, and Zn complexes are octahedral (the structure of the nickel complex is proved by X-ray diffraction analysis), whereas the palladium chelate has a square structure.

引用

页码：879 / 884

页数：6

共 29 条

[1]

Antsyshkina AS, 2000, RUSS J INORG CHEM+, V45, P1666

[2]

Antsyshkina AS, 2005, RUSS J INORG CHEM+, V50, P346

[3]

ANTSYSHKINA AS, 2000, KOORDINATS KHIM, V26, P770

[4]

Bellamy L.J., 1968, ADV INFRARED GROUP F

[5]

Bellamy L.J., 1959, INFRARED SPECTRA COM, V2nd

[6]

THE ELECTROCHEMICAL SYNTHESIS OF NEUTRAL COPPER(II) COMPLEXES OF SCHIFF-BASE LIGANDS - THE CRYSTAL-STRUCTURES OF BIS-(N-[2-(3-METHYLPYRIDYL)]-5-METHOXYSALICYLIDENEIMINATO)COPPER(II) AND BIS-(N-[2-(6-METHYLPYRIDYL)]-SALICYLIDENEIMINATO)COPPER(II) [J].

CASTINEIRAS, A ;

CASTRO, JA ;

DURAN, ML ;

GARCIAVAZQUEZ, JA ;

MACIAS, A ;

ROMERO, J ;

SOUSA, A .

POLYHEDRON, 1989, 8 (21) :2543-2549

[7]

GAMOVSKII AD, 1993, COORDIN CHEM REV, V126, P1

[8]

Electrochemical synthesis of metal (II) complexes of Schiff base 2-tosylamino (2′-pyridyl)aniline:: the crystal structure of bis-[2-tosylamino(2′-pyridyl)anilinato]cobalt(II) [J].

Garcia-Vazquez, JA ;

Romero, J ;

Duran, ML ;

Sousa, A ;

Garnovskii, AD ;

Burlov, AS ;

Garnovskii, DA .

POLYHEDRON, 1998, 17 (09) :1547-1552

[9]

Garner CR, 2005, ARS COMBINATORIA, V74, P3

[10]

Garnovskii A.D., 2003, Synthetic Coordination and Organometallic Chemistry

← 1 2 3 →