Reaction control and potential tuning in a supercritical fluid

被引：15

作者：

Clifford, AA

Pople, K

Gaskill, WJ

Bartle, KD

Rayner, CM

机构：

[1] School of Chemistry, University of Leeds, Leeds

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 06期

关键词：

D O I：

10.1039/a608066i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A maximum is found in the ratio of endo- to exo- products vs, density in the Diels-Alder reaction between cyclopentadiene and methyl acrylate in supercritical carbon dioxide and is explained by the adjustment of the position of the nearest-neighbour solvent molecules with respect to the transition states.

引用

页码：595 / 596

页数：2

共 7 条

[1] PHOTO-FRIES REARRANGEMENT OF NAPHTHYL ACETATE IN SUPERCRITICAL CARBON-DIOXIDE - CHEMICAL EVIDENCE FOR SOLVENT-SOLUTE CLUSTERING [J].