An efficient catalyst system for palladium-catalyzed borylation of aryl halides with pinacolborane

被引：80

作者：

Murata, Miki ^{[1
]}

Sambommatsu, Tomoko ^{[1
]}

Watanabe, Shinji ^{[1
]}

Masuda, Yuzuru ^{[1
]}

机构：

[1] Kitami Inst Technol, Dept Mat Sci, Kitami, Hokkaido 0908507, Japan

来源：

SYNLETT | 2006年 / 12期

关键词：

boron; palladium; catalysis; cross-coupling; ligands;

D O I：

10.1055/s-2006-947365

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The combination of Pd(dba)(2) and bis(2-di-tert-butylphospbinophenyl)ether has proven to be efficient for the crosscoupling of pinacolborane with aryl bromides and chlorides. The substrate scope is broad and the present system enables the synthesis of ortho-, meta-, and para-substituted electron-rich and -deficient arylboronates.

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页码：1867 / 1870

页数：4

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