Synthesis and structure of tetrakis carboxylato-bridged dinuclear manganese(II) quinoline complexes, with carboxylates diphenylacetate and 2,2-diphenylpropanoate

被引：10

作者：

Nakashima, M ^{[1
]}

Maruo, H

Hata, T

Tokii, T

机构：

[1] Saga Univ, Fac Culture & Educ, Dept Environm Sci, Saga 8408502, Japan

[2] Saga Univ, Fac Sci & Engn, Dept Chem, Saga 8408502, Japan

来源：

CHEMISTRY LETTERS | 1999年 / 12期

关键词：

D O I：

10.1246/cl.1999.1277

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two dinuclear Mn(II) quinoline complexes with diphenylacetate 1 or 2-2-diphenylpropanoate 2 have been prepared. Single crystal X-ray crystallography revealed the molecular structure to be the form of copper(II) acetate's. Bonding distances Mn-Mn, Mn-O, and Mn-N for 1 are 3.131(2), 2.116, and 2.193(5) Angstrom, respectively, and those for 2 are 3.168(4), 2.117, and 2.215(4) Angstrom, respectively. Anomalousness of Mn-Mn magnetic interaction of this type complexes is demonstrated.

引用

页码：1277 / 1278

页数：2

共 6 条

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