Bimolecular control over polypropene stereochemical microstructure in a well-defined two-state system and a new fundamental form: Stereogradient polypropene

被引：57

作者：

Harney, Matthew B. ^{[1
]}

Zhang, Yonghui ^{[1
]}

Sita, Lawrence R. ^{[1
]}

机构：

[1] Univ Maryland, Dept Chem & Biochem, College Pk, MD 20742 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 37期

关键词：

block copolymers; polymerization; polypropene; thermoplastic elastomers; Ziegler-Natta polymerization;

D O I：

10.1002/anie.200601616

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) A new slant on polypropene: By taking advantage of the living nature of propene polymerization in a well-defined two-state system, an unlimited variety of polypropene microstructures, including a new stereogradient structure, can be prepared with stereochemical microstructural homogeneity. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6140 / 6144

页数：5

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