Hyper-Rayleigh scattering studies of an ionic species - Solvent effect on hyperpolarizability of 1-anilinonaphthalene-8-sulfonic acid ammonium salt

被引：57

作者：

Kodaira, T

Watanabe, A

Ito, O

Matsuda, M

Clays, K

Persoons, A

机构：

[1] TOHOKU UNIV,INST CHEM REACT SCI,AOBA KU,SENDAI,MIYAGI 98077,JAPAN

[2] UNIV LEUVEN,LAB CHEM & BIOL DYNAM,B-3001 LOUVAIN,BELGIUM

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1997年 / 93卷 / 17期

关键词：

D O I：

10.1039/a702056b

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The hyperpolarizability beta of an ionic species, 1-anilinonaphthalene-8-sulfonic acid ammonium salt (ANS), was determined in various solvents by the Hyper-Rayleigh scattering (HRS) technique. Increase in the solvent polarity led to a decrease in the hyperpolarizability; i.e. beta = 37.4 +/- 2.5 x 10(-30) esu in p-dioxane and beta = 10.3 +/- 1.3 x 10(-30) esu in water. The solvent effect was explained by considering the dissociation ratio of the sulfonic acid ammonium group in solution, which influences the intramolecular donor-acceptor interaction between phenylamino and sulfonic acid ammonium groups.

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页码：3039 / 3044

页数：6

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