Chemical derivatization of endohedral metallofullerene La@C-82 with digermirane

被引：51

作者：

Akasaka, T

Kato, T

Nagase, S

Kobayashi, K

Yamamoto, K

Funasaka, H

Takahashi, T

机构：

[1] INST MOLEC SCI,OKAZAKI,AICHI 444,JAPAN

[2] TOKYO METROPOLITAN UNIV,FAC SCI,DEPT CHEM,HACHIOJI,TOKYO 19203,JAPAN

[3] POWER REACTOR & NUCL FUEL DEV CORP,TOKAI WORKS,NUCL FUEL TECHNOL DEV DIV,TOKAI,IBARAKI 31911,JAPAN

来源：

TETRAHEDRON | 1996年 / 52卷 / 14期

关键词：

D O I：

10.1016/0040-4020(96)00109-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Addition reaction of an endohedral metallofullerene La@C-82 with digermirane has been investigated by means of the mass and EPR measurements. It is found that photochemical and thermal reactions of La@C-82 with digermirane afford an exohedral adduct of the endohedral metallofullerene. This is in sharp contrast with the fact that empty fullerenes react only photochemically. The remarkable thermal reactivity of La@C-82 is ascribed to the unique electronic properties due to endohedral metal doping. (C) 1996 Elsevier Science Ltd

引用

页码：5015 / 5020

页数：6

共 28 条

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