Reactions of permethylmetallocene alkyne complexes of titanium and zirconium with tris(perfluorophenyl)borane

被引：22

作者：

Burlakov, VV

Pellny, PM

Arndt, P

Baumann, W

Spannenberg, A

Shur, VB

Rosenthal, U

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 117813, Russia

[2] Univ Rostock, Inst Organ Katalyseforsch, D-18055 Rostock, Germany

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 03期

关键词：

D O I：

10.1039/a908591b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Functionalization of the pentamethylcyclopentadienyl ligands by an electrophilic substitution of hydrogen atoms by [B(C6F5)(3)] is observed at the Cp* ligands of the alkyne complexes [Cp*M-2(eta(2)-PhC2SiMe3], connnected with (M = Ti, formation of 1) or without (M = Zr, formation of 2) loss of the alkyne and molecular hydrogen.

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页码：241 / 242

页数：2

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