Ingenane and lathyrane diterpenes from the latex of Euphorbia canariensis

被引：57

作者：

Marco, JA

SanzCervera, JF

Yuste, A

机构：

[1] Depto. de Quim. Orgánica, Universidad de Valencia, E-46100 Burjassot, Valencia

来源：

PHYTOCHEMISTRY | 1997年 / 45卷 / 03期

关键词：

Euphorbia canariensis; Euphorbiaceae; latex; diterpenes; ingenanes; ingenol esters; lathyranes; ingol epimers;

D O I：

10.1016/S0031-9422(97)00018-6

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The latex of Euphorbia canariensis yielded, in addition to five known ingenol esters, the ingenane derivatives ingenol 5-angelate 5,20-diacetate and 5-deoxyingenol 3-angelate 20-acetate, and the lathyrane derivatives 2,3-diepiingol 7,12-diacetate 8-benzoate, 2,3-diepiingol 7,12-diacetate 8-isobutyrate and 2-epiingol 3,7,12-triacetate 8-benzoate. The structures were established with the aid of spectroscopic methods, mainly NMR, and molecular mechanics calculations. They were also supported by the results of some chemical transformations. (C) 1997 Elsevier Science Ltd.

引用

页码：563 / 570

页数：8

共 24 条

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