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Mechanisms of C-H bond activation: rich synergy between computation and experiment

被引：377
作者：
Boutadla, Youcef [1 ]
Davies, David L. [1 ]
Macgregor, Stuart A. [2 ]
Poblador-Bahamonde, Amalia I. [2 ]
机构：
[1] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England
[2] Heriot Watt Univ, Sch Engn & Phys Sci, Edinburgh EH14 4AS, Midlothian, Scotland
来源：
DALTON TRANSACTIONS | 2009年 / 30期
基金：
英国工程与自然科学研究理事会;
关键词：
CARBON-HYDROGEN BONDS; PROTON-ABSTRACTION MECHANISM; CATALYZED INTRAMOLECULAR ARYLATION; LIGAND BIFUNCTIONAL CATALYSIS; TRANSITION-METAL-COMPLEXES; OXIDATIVE-ADDITION; DIHYDROGEN ACTIVATION; REDUCTIVE-ELIMINATION; MOLECULAR CATALYSTS; METHANE ACTIVATION;
D O I：
10.1039/b904967c
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Recent computational studies of C-H bond activation at late transition metal systems are discussed and processes where lone pair assistance via heteroatom co-ligands or carboxylates are highlighted as a particularly promising means of cleaving C-H bonds. The term 'ambiphilic metal ligand activation' (AMLA) is introduced to describe such reactions.
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收藏
页码：5820 / 5831
页数：12
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