Enhanced activity of Ba-doped Ir/SiO2 catalyst for NO reduction with CO in the presence of O2 and SO2

被引:57
作者
Haneda, Masaaki
Kudo, Haruko
Nagao, Yukinori
Fujitani, Tadahiro
Hamada, Hideaki
机构
[1] AIST, Res Inst Innovat Sustainable Chem, Tsukuba, Ibaraki 3058565, Japan
[2] Tokyo Univ Sci, Fac Sci & Technol, Noda, Chiba 2788510, Japan
关键词
selective reduction of NO; CO; Ir/SiO2; alkaline earth metal;
D O I
10.1016/j.catcom.2005.12.020
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 [物理化学]; 081704 [应用化学];
摘要
The effect of metal additives on the catalytic performance of Ir/SiO2 catalyst for the selective reduction of NO with CO in the presence of O-2 and SO2 was investigated. Among the 19 additives tested here, the addition of barium was the most effective to enhance the activity of Ir/SiO2 at low temperature and low SO, concentration. Catalyst characterization suggested that barium prevents catalyst deactivation as an oxidation-retardant for the active Ir metal supported on SiO2 (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:423 / 426
页数:4
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