On the importance of steady-state isotopic techniques for the investigation of the mechanism of the reverse water-gas-shift reaction

被引：90

作者：

Tibiletti, D ^{[1
]}

Goguet, A ^{[1
]}

Meunier, FC ^{[1
]}

Breen, JP ^{[1
]}

Burch, R ^{[1
]}

机构：

[1] Queens Univ Belfast, Sch Chem, CenTACat, Belfast BT41 1PB, Antrim, North Ireland

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 14期

关键词：

D O I：

10.1039/b403438d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The formation and reactivity of surface intermediates in the reverse water-gas-shift reaction on a Pt/CeO2 catalyst are critically dependent on the reaction conditions so that conclusions regarding the reaction mechanism cannot be inferred using ex operando conditions.

引用

页码：1636 / 1637

页数：2

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