Reactions of transition-metal oxo complexes with B(C6F5)3: Crystal structures of [V{OB(C6P5)(3)}(acac)(2)], [Ti{OB(C6F5)(3)}(acac)(2)] and cis-[MoO{OB(C6F5)(3)}(acac)(2)] (acac equals acetylacetonate)

被引：37

作者：

Galsworthy, JR ^{[1
]}

Green, MLH ^{[1
]}

Muller, M ^{[1
]}

Prout, K ^{[1
]}

机构：

[1] CHEM CRYSTALLOG LAB,OXFORD OX1 3PD,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 08期

关键词：

D O I：

10.1039/a608140a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The transition-metal oxo complexes [VO(acac)(2)],[{TiO(acac)(2)}(2)] and cis-[MoO2(acac)(2)] (acac = C5H7O2) reacted with the strong Lewis acid B(C6F5)(3) to give the structurally characterized complexes [V{OB(C6F5)(3)}(acac)(2)], [Ti{OB(C6F5)(3)}(acac)(2)] and cis-[MoO{OB(C6F5)(3)}(acac)(2)]. The M=O-B moiety is essentially linear.

引用

页码：1309 / 1313

页数：5

共 21 条

[1] MONONUCLEAR AND DINUCLEAR TITANIUM(III) TITANIUM(IV) COMPLEXES WITH 1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE(L) - CRYSTAL-STRUCTURES OF A COMPOSITIONALLY DISORDERED GREEN AND A BLUE FORM OF [LTICL3] - STRUCTURES OF [LTI(O)(NCS)2], [LTI(OCH3)BR2](CLO4), AND [L2TI2(O)2F2(MU-F)](PF6)
BODNER, A
JESKE, P
WEYHERMULLER, T
WIEGHARDT, K
DUBLER, E
SCHMALLE, H
NUBER, B
[J]. INORGANIC CHEMISTRY, 1992, 31 (18) : 3737 - 3748
[2] VANADYL AS A DONOR GROUP IN HETEROBIMETALLIC COMPLEXES
CASHIN, B
CUNNINGHAM, D
GALLAGHER, JF
MCARDLE, P
HIGGINS, T
[J]. POLYHEDRON, 1989, 8 (13-14) : 1753 - 1755
[3] POLYFLUOROARYL ORGANOMETALLIC COMPOUNDS .2. PENTAFLUOROPHENYLBORON HALIDES AND SOME DERIVED COMPOUNDS
CHAMBERS, RD
CHIVERS, T
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1965, (JUL): : 3933 - &
[4] Electronic structure of bis(2,4-pentanedionato-O,O')oxovanadium(IV). A photoelectron spectroscopy, electronic spectroscopy, and ab initio molecular orbital study
DiBella, S
Lanza, G
Gulino, A
Fragala, I
[J]. INORGANIC CHEMISTRY, 1996, 35 (13) : 3885 - 3890
[5] DODGE RP, 1965, J CHEM PHYS, V43, P3111
[6] X-RAY CRYSTAL-STRUCTURE OF W(OALBR3)(CH2T-BU)3BR, A MODEL FOR CATALYST COCATALYST INTERACTION
FISCHER, J
KRESS, J
OSBORN, JA
RICARD, L
WESOLEK, M
[J]. POLYHEDRON, 1987, 6 (10) : 1839 - 1842
[7] GEWIRTH D, 1995, HKL MANUAL
[8] GREEN MLH, 1985, J CHEM SOC CHEM COMM, P1853
[9] KRESS J, 1982, J CHEM SOC CHEM COMM, P1039
[10] SPECTROSCOPIC AND EQUILIBRIUM STUDIES OF ADDUCT FORMATION BETWEEN BIS(2,4-PENTADIONATO)OXOVANADIUM(IV) AND SUBSTITUTED PYRIDINES
MACAZAGA, MJ
GARCIAVAZQUEZ, JA
MEDINA, RM
MASAGUER, JR
[J]. TRANSITION METAL CHEMISTRY, 1983, 8 (04) : 215 - 218

← 1 2 3 →