Chlorides, oxochlorides, and oxoacids of 1,8-diphosphanaphthalene:: A system with imposed close P•••P interaction

被引：30

作者：

Kilian, P ^{[1
]}

Milton, HL ^{[1
]}

Slawin, AMZ ^{[1
]}

Woollins, JD ^{[1
]}

机构：

[1] Univ St Andrews, Dept Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

INORGANIC CHEMISTRY | 2004年 / 43卷 / 07期

关键词：

D O I：

10.1021/ic035364h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Several new 1,8-diphosphanaphthalene oxochloro compounds and oxoacids were prepared and fully characterized. The new compounds are discussed in the broader context with other known congeners to demonstrate the variability of the diphosphanaphthalene scaffolding's bonding patterns. Three principal modes of interaction of the phosphorus moieties were observed in the series: bonding, bridging, and repulsive, resulting respectively in none, moderate, and substantial crowding and distortions. The unexpected dimeric diphosphaacenaphthene anion has been obtained from disproportionative hydrolysis of Nap(PCl2)(2) (Nap = naphthalene- 1,8-diyl).

引用

页码：2252 / 2260

页数：9

共 22 条

[1]

CORBRIDGE DEC, 1985, PHOSPHORUS OUTLINE C, P232

[2] THE BEHAVIOR OF SOME ORGANOPHOSPHORUS(V) COMPOUNDS IN STRONGLY ACIDIC SOLVENTS .1. MONOPHENYL DERIVATIVES [J].

DILLON, KB ;

NISBET, MP ;

WADDINGTON, TC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1981, (01) :212-218

[3] The anionic zirconocene trihydride: [Cp*2ZrH3](-) [J].

Etkin, N ;

Hoskin, AJ ;

Stephan, DW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (47) :11420-11424

[4]

KABACHNIK MM, 1982, ZH OBSHCH KHIM+, V52, P763

[5]

KABACHNIK MM, 1982, J GEN CHEM USSR, V52, P662

[6] 1,8-bis(phosphanyl)naphthalenes: 1,8-bis[(diethylamino)phosphanyl]naphthalene, 1,8-bis(dichlorophosphanyl)naphthalene, and 1,3-dichloro-2,3-dihydro-1,3-dioxo-2-oxa-1,3-diphosphaphenalene [J].

Karacar, A ;

Thonnessen, H ;

Jones, PG ;

Bartsch, R ;

Schmutzler, R .

CHEMISCHE BERICHTE-RECUEIL, 1997, 130 (10) :1485-1489

[7] Preparation and structures of 1-dimethylamino-2-bis(dimethylamino)- and 1-chloro-2-bis(diethylamino)-1-phospha-2-phosphonium acenaphthene:: the first examples of the 1,2-dihydro-1,2-diphospha-acenaphthene ring system [J].

Karaçar, A ;

Freytag, M ;

Thönnessen, H ;

Jones, PG ;

Bartsch, R ;

Schmutzler, R .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 643 :68-80

[8]

Karaçar A, 2001, Z ANORG ALLG CHEM, V627, P2589, DOI 10.1002/1521-3749(200112)627:12<2589::AID-ZAAC2589>3.0.CO

[9]

2-R

[10] Reaction of naphthalenedithiadiphosphetanedisulphide with ethylene glycol [J].

Kilian, P ;

Jiritouzin ;

Marek, J ;

Woollins, JD ;

Novosad, J .

MAIN GROUP CHEMISTRY, 1996, 1 (04) :425-429

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