Zinc-67 NMR study of tetrahedral and octahedral zinc sites with symmetrical oxygen, nitrogen, and sulfur ligands

被引：27

作者：

Sham, S ^{[1
]}

Wu, G ^{[1
]}

机构：

[1] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1999年 / 77卷 / 11期

关键词：

Zn-67; NMR; nuclear quadrupolar coupling constant; ligand exchange;

D O I：

10.1139/cjc-77-11-1782

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report a Zn-67 nuclear magnetic resonance (NMR) study of compounds containing zinc ions coordinated by oxygen, nitrogen, and sulfur ligands. New information concerning Zn-67 nuclear quadrupole coupling constants (NQCC) and chemical shift was obtained from magic-angle spinning (MAS) spectra of solid compounds containing both natural abundance and enriched Zn-67 isotopes. Rapid ligand exchange processes of [Zn(thiourea)(4)](2+) in aqueous solutions were also observed.

引用

页码：1782 / 1787

页数：6

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