EPR and TL correlation in some powdered Greek white marbles

被引:9
作者
Baïetto, V [1 ]
Villeneuve, G [1 ]
Guibert, P [1 ]
Schvoerer, M [1 ]
机构
[1] Univ Bordeaux 3, CNRS, Ctr Rech Phys Appliquee Archeol, F-33405 Talence, France
关键词
archaeomaterial; electron paramagnetic resonance (EPR); thermoluminescence (TL); white marble; calcite;
D O I
10.1016/S0969-8043(99)00120-7
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Thermoluminescence of white powdered marble samples, chosen to display different EPR spectra, were studied. Two peaks at 280 degrees C and 360 degrees C can be observed among the TL glow curves while the EPR spectra exhibit two signals: the A signal with g(perpendicular to) = 2.0038 and g(parallel to) = 2.0024 due to the SO3- centre and the B one with g(1) = 2.0005; g(2) = 2.0001; g(3) = 1.9998 due to mechanical powder reduction (drilling). Owing to heating and simultaneous experiments, a correlation have been established: the 280 degrees C TL peak is associated to the A signal and thus to the SO3- centre and the 360 degrees C TL peak is caused by mechanical treatment corresponding to the B EPR signal. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:229 / 235
页数:7
相关论文
共 27 条
[1]  
Bahain Jean-Jacques, 1995, Quaternaire, V6, P13
[2]   Investigation of electron paramagnetic resonance peaks in some powdered Greek white marbles [J].
Baïetto, V ;
Villeneuve, G ;
Schvoerer, M ;
Bechtel, F ;
Herz, N .
ARCHAEOMETRY, 1999, 41 :253-265
[3]  
BARABAS M, 1992, NUCL TRACKS RAD MEAS, V20, P453
[4]   Q-BAND ESR STUDIES OF FOSSIL TEETH - CONSEQUENCES FOR ESR DATING [J].
BOUCHEZ, R ;
COX, R ;
HERVE, A ;
LOPEZCARRANZA, E ;
MA, JL ;
PIBOULE, M ;
POUPEAU, G ;
REY, P .
QUATERNARY SCIENCE REVIEWS, 1988, 7 (3-4) :497-501
[5]   THERMO-LUMINESCENCE FROM NATURAL CALCITES [J].
CALDERON, T ;
AGUILAR, M ;
JAQUE, F ;
COYYLL, R .
JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1984, 17 (11) :2027-2038
[6]  
DEBUYST R, 1991, NUCL TRACKS RAD MEAS, V18, P193
[7]  
FALGUERES C, 1994, CR ACAD SCI II, V319, P261
[8]   ESR-DATING - PROBLEMS ENCOUNTERED IN THE EVALUATION OF THE NATURALLY ACCUMULATED DOSE [AD] OF SECONDARY CARBONATES [J].
GRUN, R ;
DECANNIERE, P .
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 1984, 85 (04) :213-226
[9]  
GRUN R, 1991, NUCL TRACKS RAD MEAS, V18, P143
[10]   TL AND RADIOCARBON DATING OF NEOLITHIC SEPULTURES FROM SUDAN - INTERCOMPARISON OF RESULTS [J].
GUIBERT, P ;
NEY, C ;
BECHTEL, F ;
SCHVOERER, M ;
GEUS, F .
RADIATION MEASUREMENTS, 1994, 23 (2-3) :393-398