A hierarchical structure for apatite crystals

被引:16
作者
Dorozhkin, Sergey V.
机构
[1] 123242 Moscow D-242
关键词
D O I
10.1007/s10856-006-0701-x
中图分类号
R318 [生物医学工程];
学科分类号
0831 ;
摘要
Based on the experimental results taken from the references, a reasonable hierarchical structure of apatite (both fluorapatite and hydroxyapatite) crystals has been proposed for the first time. The structure consists of four levels of the hierarchy: the smallest level is made of single unit-cells and/or Posner's clusters with the linear dimensions slightly below 1 nm, the second level comprises X-ray coherent scattering blocks of 50-80 nm in size, the third level is represented by dislocation blocks of 0.3-2.0 mu m in size and, finally, there are macroblocks of 35-50 mu m in size.
引用
收藏
页码:363 / 366
页数:4
相关论文
共 28 条
[1]  
[Anonymous], 1994, STUDIES INORGANIC CH
[2]  
BECKER P, 1989, FERTILISER SCI TECHN
[3]  
CHAIKINA MV, 1983, REPORTS SIBERIAN B C, V4, P24
[4]  
CHAIKINA MV, 1983, REPORTS SIBERIAN B C, V4, P15
[5]   STRUCTURE OF INITIAL CRYSTALS FORMED DURING HUMAN AMELOGENESIS [J].
CUISINIER, FJG ;
VOEGEL, JC ;
YACAMAN, J ;
FRANK, RM .
JOURNAL OF CRYSTAL GROWTH, 1992, 116 (3-4) :314-318
[6]  
Currey J.D., 2002, Bones: structure and mechanics
[7]   CHEMICAL PREPARATION OF DIELECTRICS FOR STUDYING THEIR MICROTOPOGRAPHY BY THE SEM [J].
DOROZHKIN, SV ;
NIKOLAEV, AL ;
MELIKHOV, IV ;
SAPARIN, GV ;
BLIADZE, VG .
SCANNING, 1992, 14 (02) :112-117
[8]   Mechanism of solid-state conversion of non-stoichiometric hydroxyapatite to diphase calcium phosphate [J].
Dorozhkin, SV .
RUSSIAN CHEMICAL BULLETIN, 2003, 52 (11) :2369-2375
[9]   Fundamentals of the wet-process phosphoric acid production .1. Kinetics and mechanism of the phosphate rock dissolution [J].
Dorozhkin, SV .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1996, 35 (11) :4328-4335
[10]   Mechanism of the solid-state transformation of a calcium-deficient hydroxyapatite (CDHA) into biphasic calcium phosphate (BCP) at elevated temperatures [J].
Dorozhkina, EI ;
Dorozhkin, SV .
CHEMISTRY OF MATERIALS, 2002, 14 (10) :4267-4272