The first asymmetric synthesis of chiral ruthenium tris(bipyridine) from racemic ruthenium bis(bipyridine) complexes

被引：24

作者：

Hesek, D

Inoue, Y

Ishida, H

Everitt, SRL

Drew, MGB

机构：

[1] JST, ERATO, Inoue Photochirogenesis Project, Osaka 5600085, Japan

[2] Univ Reading, Dept Chem, Reading RG6 6AD, Berks, England

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 15期

关键词：

asymmetric synthesis; chirality; sulfoxides; ruthenium;

D O I：

10.1016/S0040-4039(00)00230-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first 'one-pot' asymmetric synthesis of ruthenium tris(bipyridine) derivatives starting from corresponding racemic ruthenium bis(bipyridine) complexes is described. This is achieved through the stereocontrolled formation of reactive intermediates derived from (R)-(+)- or (S)-(-)-methyl p-tolyl sulfoxide, which can be easily converted to the products with a retention of configuration at the metal center. (C) 2000 Elsevier Science Ltd. All rights reserved.

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页码：2617 / 2620

页数：4

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