Novel T-shaped 14-electron platinum(II) complexes stabilized by one agostic interaction

被引：78

作者：

Baratta, W ^{[1
]}

Stoccoro, S

Doppiu, A

Herdtweck, E

Zucca, A

Rigo, P

机构：

[1] Univ Udine, Dipartimento Sci & Technol Chim, Via Cotonificia 108, I-33100 Udine, Italy

[2] Univ Sassari, Dipartimento Chim, I-07100 Sassari, Italy

[3] Tech Univ Munich, Inst Anorgan Chem, D-85747 Garching, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 01期

关键词：

agostic interactions; phosphane ligands; carbon bond; platinum; X-ray diffraction;

D O I：

10.1002/anie.200390035

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The stereoelectronic properties of the PR2(2,6-Me2C6H3) (R=Ph, Cy) ligand can be used to stabilize an unprecedented class of 14-electron platinum(II) complexes. The X-ray analysis of the cyclometalated cyclohexyl derivative reveals an agostic interaction between the Pt center and an o-methyl moiety (see picture). The fast and reversible formation of three-coordinate platinum-hydrido complexes occurs by reaction with H2, and is achieved through the cleavage of a platinum-carbon bond.

引用

页码：105 / 108

页数：4

共 46 条

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