Isocyanate and carbodiimide synthesis by nitrene-group-transfer from a nickel(II) imido complex

被引：97

作者：

Mindiola, DJ ^{[1
]}

Hillhouse, GL ^{[1
]}

机构：

[1] Univ Chicago, Dept Chem, Searle Chem lab, Chicago, IL 60637 USA

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 17期

关键词：

D O I：

10.1039/b204846a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The imido complex (dtbpe) Ni{N(2,6-(CHMe2)(2)C6H3)} reacts with CO and CNCH2Ph with addition at the Ni-N bond to give (dtbpe) Ni{C, N:eta(2)-C(O) N(2,6-(CHMe2)(2)C6H3)} and (dtbpe) Ni{C, N:eta(2)-C( NCH2Ph) N(2,6-(CHMe2)(2)C6H3)}; both complexes react further with CO to liberate the isocyanate and carbodiimide ligands with formation of (dtbpe) Ni( CO)(2).

引用

页码：1840 / 1841

页数：2

共 18 条

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