Ferrocenylsilylation of dendrons: a fast convergent route to redox-stable ferrocene dendrimers

被引：103

作者：

Nlate, S

Ruiz, J

Blais, JC

Astruc, D ^{[1
]}

机构：

[1] Univ Bordeaux 1, CNRS, UMR5802, LCOO,Grp Chim Supramol Metaux Transit, F-33405 Talence, France

[2] Univ Paris 06, CNRS, EP 103, Lab Chim Struct Organ & Biol, F-75252 Paris, France

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 05期

关键词：

D O I：

10.1039/a908791e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A 54-ferrocene dendrimer is synthesized by a convergent route and can be used to modify a Pt electrode in CH2Cl2; it can be reversibly oxidized in DMF in a single 54-electron wave (and with NO+).

引用

页码：417 / 418

页数：2

共 45 条

[1] ELECTRODES MODIFIED WITH ELECTROACTIVE FILMS OF ORGANOMETALLIC DENDRIMERS [J].

ALONSO, B ;

MORAN, M ;

CASADO, CM ;

LOBETE, F ;

LOSADA, J ;

CUADRADO, I .

CHEMISTRY OF MATERIALS, 1995, 7 (08) :1440-1442

[2] ORGANOMETALLIC SILICON DENDRIMERS [J].

ALONSO, B ;

CUADRADO, I ;

MORAN, M ;

LOSADA, J .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (22) :2575-2576

[3]

[Anonymous], ADV DENDR MACROMOL

[4]

ARDOIN N, 1995, B SOC CHIM FR, V132, P875

[5]

ASTRUC D, 1995, ELECT TRANSFER RADIC, pCH4

[6]

ASTRUC D, MOL ELECT

[7] Designing dendrimers based on transition metal complexes. Light-harvesting properties and predetermined redox patterns [J].

Balzani, V ;

Campagna, S ;

Denti, G ;

Juris, A ;

Serroni, S ;

Venturi, M .

ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (01) :26-34

[8]

BALZANI V, 1991, SUPRAMOLECULAR CHEM

[9] Asymmetric redox-active dendrimers containing a ferrocene subunit. Preparation, characterization, and electrochemistry [J].

Cardona, CM ;

Kaifer, AE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (16) :4023-4024

[10] Redox-active ferrocenyl dendrimers and polymers in solution and immobilised on electrode surfaces [J].

Casado, CM ;

Cuadrado, I ;

Morán, M ;

Alonso, B ;

García, B ;

González, B ;

Losada, J .

COORDINATION CHEMISTRY REVIEWS, 1999, 185-6 :53-79

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