First example of a silica gel-supported optically active Mn(III)-salen complex as a heterogeneous asymmetric catalyst in the epoxidation of olefins

被引：76

作者：

Pini, D ^{[1
]}

Mandoli, A ^{[1
]}

Orlandi, S ^{[1
]}

Salvadori, P ^{[1
]}

机构：

[1] Dipartimento Chim & Chim Ind, CNR, Ctr Studio Macromol Stereordin & Otticamen Att, I-56126 Pisa, Italy

来源：

TETRAHEDRON-ASYMMETRY | 1999年 / 10卷 / 20期

关键词：

D O I：

10.1016/S0957-4166(99)00426-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An optically active Mn(III)-salen complex was supported on silica gel materials: the insoluble systems obtained were employed as catalysts in the asymmetric epoxidation of some aromatic olefins. Enantiomeric excess values up to 58% were obtained. (C) 1999 Elsevier Science Ltd. All rights reserved.

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页码：3883 / 3886

页数：4

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