Imaging of the 3D Nanostructure of a Polymer Solar Cell by Electron Tomography

被引:91
作者
Andersson, B. Viktor [1 ]
Herland, Anna [1 ]
Masich, Sergej [2 ]
Inganas, Olle [1 ]
机构
[1] Linkoping Univ, IFM, SE-58183 Linkoping, Sweden
[2] Karolinska Inst, Dept Cell & Mol Biol, Stockholm 17177, Sweden
关键词
NANOSCALE MORPHOLOGY; PERFORMANCE; BLENDS; PCBM; MICROSCOPY; SOLVENT;
D O I
10.1021/nl803676e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Electron tomography has been used for analyzing the active layer in a polymer solar cell, a bulk heterojunction of an alternating copolymer of fluorene and a derivative of fullerene. The method supplies a three-dimensional representation of the morphology of the film, where domains with different scattering properties may be distinguished. The reconstruction shows good contrast between the two phases included in the film and demonstrates that electron tomography is an adequate tool for investigations of the three-dimensional nanostructure of the amorphous materials used in polymer solar cells.
引用
收藏
页码:853 / 855
页数:3
相关论文
共 20 条
[1]  
[Anonymous], 1995, SCIENCE
[2]   Mapping molecular landscapes inside cells [J].
Baumeister, W .
BIOLOGICAL CHEMISTRY, 2004, 385 (10) :865-872
[3]   Multilayer formation in spin-coated thin films of low-bandgap polyfluorene: PCBM blends [J].
Björström, CM ;
Bernasik, A ;
Rysz, J ;
Budkowski, A ;
Nilsson, S ;
Svensson, M ;
Andersson, MR ;
Magnusson, KO ;
Moons, E .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2005, 17 (50) :L529-L534
[4]   Characterization of polymer solar cells by TOF-SIMS depth profiling [J].
Bulle-Lieuwma, CWT ;
van Gennip, WJH ;
van Duren, JKJ ;
Jonkheijm, P ;
Janssen, RAJ ;
Niemantsverdriet, JW .
APPLIED SURFACE SCIENCE, 2003, 203 :547-550
[5]   Simultaneous use of small- and wide-angle X-ray techniques to analyze nanometerscale phase separation in polymer heterojunction solar cells [J].
Chiu, Mao-Yuan ;
Jeng, U-Ser ;
Su, Chiu-Hun ;
Liang, Keng S. ;
Wei, Kung-Hwa .
ADVANCED MATERIALS, 2008, 20 (13) :2573-+
[6]   Nanoscale charge transport and internal structure of bulk heterojunction conjugated polymer/fullerene solar cells by scanning probe microscopy [J].
Dante, Mark ;
Peet, Jeffrey ;
Nguyen, Thuc-Quyen .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (18) :7241-7249
[7]  
DOUBERET O, 2007, PROG PHOTOVOLTAICS, V15, P713
[8]   Image processing and 3-D reconstruction in electron microscopy [J].
Fernandez, JJ ;
Sorzano, COS ;
Marabini, R ;
Carazo, JM .
IEEE SIGNAL PROCESSING MAGAZINE, 2006, 23 (03) :84-94
[9]   Nanoscale morphology of conjugated polymer/fullerene-based bulk-heterojunction solar cells [J].
Hoppe, H ;
Niggemann, M ;
Winder, C ;
Kraut, J ;
Hiesgen, R ;
Hinsch, A ;
Meissner, D ;
Sariciftci, NS .
ADVANCED FUNCTIONAL MATERIALS, 2004, 14 (10) :1005-1011
[10]   3D nanometer-scale study of coexisting bicontinuous morphologies in a block copolymer/homopolymer blend [J].
Jinnai, Hiroshi ;
Hasegawa, Hirokazu ;
Nishikawa, Yukihiro ;
Sevink, G. J. Agur ;
Braunfeld, Michael B. ;
Agard, David A. ;
Spontak, Richard J. .
MACROMOLECULAR RAPID COMMUNICATIONS, 2006, 27 (17) :1424-1429