Polymerisation of 1-iodohexa-1,3,5-triyne and hexa-1,3,5-triyne: a new synthesis of carbon nanotubes at low temperatures

被引:34
作者
Hlavaty, J
Kavan, L
Kasahara, N
Oya, A
机构
[1] J Heyrovsky Inst Phys Chem, CZ-18213 Prague 8, Czech Republic
[2] Gunma Univ, Fac Engn, Gunma 3768515, Japan
关键词
D O I
10.1039/b000895h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
1-Iodohexa-1,3,5-triyne (I) and hexa-1,3,5-triyne (II) spontaneously polymerise in aprotic solution to form a solid carbonaceous product which contains polyyne-like structures and multi-walled carbon nanotubes with outer diameter ca. 10-20 nm and length 100-200 nm.
引用
收藏
页码:737 / 738
页数:2
相关论文
共 7 条
[1]  
BRANDSMA L, 1987, PREPARATIVE POLAR OR, V1
[2]  
HLAVATY J, IN PRESS CARBON
[3]   Electrochemical carbon [J].
Kavan, L .
CHEMICAL REVIEWS, 1997, 97 (08) :3061-3082
[4]   Carbonization of highly oriented poly(tetrafluoroethylene) [J].
Kavan, L ;
Dousek, FP ;
Janda, P ;
Weber, J .
CHEMISTRY OF MATERIALS, 1999, 11 (02) :329-335
[5]   Carbon nanostructures from perfluorinated hydrocarbons [J].
Kavan, L ;
Hlavaty, J .
CARBON, 1999, 37 (11) :1863-1865
[6]   Transformation of polyyne-containing carbon to nanoscale carbon tubules [J].
Kawase, N ;
Yasuda, A ;
Matsui, T ;
Yamaguchi, C ;
Matsui, H .
CARBON, 1999, 37 (03) :522-524
[7]   ON THE STABILITY OF POLYYNE [J].
SPRINGBORG, M ;
KAVAN, L .
CHEMICAL PHYSICS, 1992, 168 (2-3) :249-258