Post-metallocenes: Catalytic perfomance of new bis(salicylaldiminato) zirconium complexes for ethylene polymerization

被引:97
作者
Matsui, S [1 ]
Mitani, M [1 ]
Saito, J [1 ]
Matsukawa, N [1 ]
Tanaka, H [1 ]
Nakano, T [1 ]
Fujita, T [1 ]
机构
[1] Mitsui Chem Inc, Mat Sci Lab, Sodegaura, Chiba 2990265, Japan
关键词
D O I
10.1246/cl.2000.554
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
New bis(salicylaldiminato) zirconium complexes were synthesized and investigated as ethylene polymerization catalysts. As a result, we demonstrated that high molecular weight (Mw: 71.6 x 10(4)) and super high activity (2096 kg-PE/mmol-Zr-h) were accomplished by changing the ligand structure.
引用
收藏
页码:554 / 555
页数:2
相关论文
共 15 条
[1]   BRIDGED BIS (FLUORENYL) COMPLEXES OF ZIRCONIUM AND HAFNIUM AS HIGHLY REACTIVE CATALYSTS IN HOMOGENEOUS OLEFIN POLYMERIZATION - MOLECULAR-STRUCTURES OF (C13H9-C2H4-C13H9) AND (ETA(5)ETA(5)-C13H8-C2H4-C13H8)ZRCL2 [J].
ALT, HG ;
MILIUS, W ;
PALACKAL, SJ .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 472 (1-2) :113-118
[2]   STEREOSPECIFIC OLEFIN POLYMERIZATION WITH CHIRAL METALLOCENE CATALYSTS [J].
BRINTZINGER, HH ;
FISCHER, D ;
MULHAUPT, R ;
RIEGER, B ;
WAYMOUTH, RM .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (11) :1143-1170
[3]   Novel olefin polymerization catalysts based on iron and cobalt [J].
Britovsek, GJP ;
Gibson, VC ;
Kimberley, BS ;
Maddox, PJ ;
McTavish, SJ ;
Solan, GA ;
White, AJP ;
Williams, DJ .
CHEMICAL COMMUNICATIONS, 1998, (07) :849-850
[4]  
Britovsek GJP, 1999, ANGEW CHEM INT EDIT, V38, P428, DOI 10.1002/(SICI)1521-3773(19990215)38:4<428::AID-ANIE428>3.0.CO
[5]  
2-3
[6]   Highly electrophilic olefin polymerization catalysts. Quantitative reaction coordinates for fluoroarylborane/alumoxane methide abstraction and ion-pair reorganization in group 4 metallocene and "constrained geometry" catalysts [J].
Deck, PA ;
Beswick, CL ;
Marks, TJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (08) :1772-1784
[7]   Computer design of living olefin polymerization catalysts: A combined density functional theory and molecular mechanics study [J].
Deng, LQ ;
Ziegler, T ;
Woo, TK ;
Margl, P ;
Fan, LY .
ORGANOMETALLICS, 1998, 17 (15) :3240-3253
[8]   Towards an order-N DFT method [J].
Guerra, CF ;
Snijders, JG ;
te Velde, G ;
Baerends, EJ .
THEORETICAL CHEMISTRY ACCOUNTS, 1998, 99 (06) :391-403
[9]   NEW PD(II)-BASED AND NI(II)-BASED CATALYSTS FOR POLYMERIZATION OF ETHYLENE AND ALPHA-OLEFINS [J].
JOHNSON, LK ;
KILLIAN, CM ;
BROOKHART, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (23) :6414-6415
[10]   Living polymerization of alpha-olefins using Ni-II-alpha-diimine catalysts. Synthesis of new block polymers based on alpha-olefins [J].
Killian, CM ;
Tempel, DJ ;
Johnson, LK ;
Brookhart, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (46) :11664-11665