New preparative access to and the crystal and molecular structures of cis-[PtCl2(CO)(2)]

被引：33

作者：

Bagnoli, F

DellAmico, DB

Calderazzo, F

Englert, U

Marchetti, F

Herberich, GE

Pasqualetti, N

Ramello, S

机构：

[1] UNIV PISA,DIPARTIMENTO CHIM,I-56126 PISA,ITALY

[2] RHEIN WESTFAL TH AACHEN,INST ANORGAN CHEM,D-52074 AACHEN,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 23期

关键词：

D O I：

10.1039/dt9960004317

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

cis-Dicarbonyldichloroplatinum(II) has been found to be the thermodynamically stable species arising from: (a) carbonylation of [NBu(4)](2)[PtCl4] in the presence of AlCl3, (b) chlorination of [PtI2(CO)(2)]-[Pt2I4(CO)(2)] with SO2Cl2 under CO and (c) carbonylation of PtCl2; the crystal and molecular structures of cis-[PtCl2(CO)(2)] showed a short C-O distance [average 1.115(7) Angstrom] and intermolecular Pt ... Pt and C ... Cl contacts of less than 3.4 Angstrom.

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页码：4317 / 4318

页数：2

相关论文

共 41 条

[1] DICARBONYLGOLD(I) HEXAFLUOROURANATE(VI), AU(CO)2UF6 [J].

ADELHELM, M ;

BACHER, W ;

HOHN, EG ;

JACOB, E .

CHEMISCHE BERICHTE, 1991, 124 (07) :1559-1561

[2] CHEMISTRY AT DIPLATINUM CENTERS [J].

ANDERSON, GK .

ADVANCES IN ORGANOMETALLIC CHEMISTRY, VOL 35, 1993, 35 :1-39

[3] CARBONYL-COMPLEXES OF NOBLE-METALS WITH HALIDE LIGANDS .1. PLATINUM(II) HALIDE EXCHANGE, DIMERIZATION, ISOMERIZATION, C-13 NMR DATA AND CRYSTAL AND MOLECULAR-STRUCTURE OF PT2I4(CO)2 [J].

ANDREINI, BP ;

DELLAMICO, DB ;

CALDERAZZO, F ;

VENTURI, MG ;

PELIZZI, G ;

SEGRE, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 354 (03) :357-368

[4]

[Anonymous], COMPT REND

[5] CARBON-MONOXIDE AS A SIGMA-DONOR LIGAND IN COORDINATION CHEMISTRY [J].

AUBKE, F ;

WANG, C .

COORDINATION CHEMISTRY REVIEWS, 1994, 137 :483-524

[6] On the existence of a pyramidality effect in d(8)center dot center dot center dot d(8) contacts. Theoretical study and structural correlation [J].

Aullon, G ;

Alemany, P ;

Alvarez, S .

INORGANIC CHEMISTRY, 1996, 35 (17) :5061-5067

[7]

Belli Dell&PRIME

[8]

Amico D., 1996, ANGEW CHEM, V108, P1430

[9] LINEAR-CHAIN PLATINUM(II) DITHIOCARBOXYLATES - CRYSTAL-STRUCTURE OF TETRAKIS(PHENYLDITHIOACETATO)DIPLATINUM(II) [J].

BELLITTO, C ;

BONAMICO, M ;

DESSY, G ;

FARES, V ;

FLAMINI, A .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (01) :35-40

[10] Syntheses and vibrational and C-13 MAS-NMR spectra of bis(carbonyl)mercury(II) undecafluorodiantimonate(V) ([Hg(CO)(2)][Sb2F11](2)) and of bis(carbonyl) dimercury(I) undecafluorodiantimonate ([Hg-2(CO)(2)][Sb2F11](2)) and the molecular structure of [Hg(CO)(2)][Sb2F11](2) [J].

Bodenbinder, M ;

BalzerJollenbeck, G ;

Willner, H ;

Batchelor, RJ ;

Einstein, FWB ;

Wang, C ;

Aubke, F .

INORGANIC CHEMISTRY, 1996, 35 (01) :82-92

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