Cyclopalladated ferrocenyl amines as enantioselective catalysts for the rearrangement of allylic imidates to allylic amides

被引：91

作者：

Hollis, TK ^{[1
]}

Overman, LE ^{[1
]}

机构：

[1] UNIV CALIF IRVINE,DEPT CHEM,IRVINE,CA 92697

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 51期

关键词：

D O I：

10.1016/S0040-4039(97)10385-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first examples of the use of cyclopalladated complexes in enantioselective catalysis are reported. Cyclopalladated ferrocenyl amine Gf promotes the rearrangement of some 2-alkenyl imidates to allylically transposed amides in excellent yield and moderate enantioselectivity. (C) 1997 Elsevier Science Ltd.

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页码：8837 / 8840

页数：4

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