Suzuki-type coupling of chloroarenes with arylboronic acids catalysed by nickel complexes

被引：171

作者：

Indolese, AF

机构：

[1] Catalysis Research, Novartis Services AG

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 20期

关键词：

PALLADIUM;

D O I：

10.1016/S0040-4039(97)00707-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A Suzuki-type cross-coupling reaction of aryl chlorides with arylboronic acids using nickel-catalysts is described. The best results were obtained at 95 degrees C in the presence of K3PO4 and in dioxane using Ni(dppf)Cl-2. Unsymmetrical biaryls with both electron-withdrawing and electron-donating functional groups were obtained in high yields. (C) 1997 Elsevier Science Ltd.

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页码：3513 / 3516

页数：4

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