A novel dodecanuclear chromium(III) cage: structural control by choice of leaving group

被引：33

作者：

Parsons, S ^{[1
]}

Smith, AA ^{[1
]}

Winpenny, REP ^{[1
]}

机构：

[1] Univ Edinburgh, Dept Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 07期

关键词：

D O I：

10.1039/b001140l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and structural characterisation of a novel metal polyhedron is reported, involving chromium(III) and isobutyrate; comparison of this product with those obtained using different carboxylates suggests that the leaving group-which can be carboxylate, water or both-strongly influences the structure found.

引用

页码：579 / 580

页数：2

共 14 条

[1]

Atkinson IM, 1999, CHEM COMMUN, P285

[2] Distorted MnIVMn3III cubane complexes as single-molecule magnets [J].

Aubin, SMJ ;

Wemple, MW ;

Adams, DM ;

Tsai, HL ;

Christou, G ;

Hendrickson, DN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (33) :7746-7754

[3]

BEURSKENS PT, 1996, DIRDIF 96 PROGRAM SY

[4] Desolvating cubes and linking prisms: Routes to high-nuclearity cobalt complexes [J].

Brechin, EK ;

Harris, SG ;

Parsons, S ;

Winpenny, REP .

CHEMICAL COMMUNICATIONS, 1996, (12) :1439-1440

[5] Nanoscale cages of manganese and nickel with "rock salt" cores [J].

Brechin, EK ;

Clegg, W ;

Murrie, M ;

Parsons, S ;

Teat, SJ ;

Winpenny, REP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (29) :7365-7366

[6] THE [CO4O4](4+) CUBANE AS A QUADRUPLY-BRIDGING UNIT - THE MIXED-VALENCE CLUSTER [CO8O4(O(2)CPH)(12)(SOLV)(4)] (SOLV=DMF, MECN, H2O) [J].

DIMITROU, K ;

SUN, JS ;

FOLTING, K ;

CHRISTOU, G .

INORGANIC CHEMISTRY, 1995, 34 (16) :4160-4166

[7] Bis-bipyridine ligands in cobalt carboxylate cluster chemistry: A mixed-valence (4Co(II), 4Co(III)) complex with a face-sharing, triple-cubane structure [J].

Grillo, VA ;

Sun, ZM ;

Folting, K ;

Hendrickson, DN ;

Christou, G .

CHEMICAL COMMUNICATIONS, 1996, (19) :2233-2234

[8]

Mabbs FE, 1999, CHEM COMMUN, P643

[9]

Raptis RG, 1999, ANGEW CHEM INT EDIT, V38, P1632, DOI 10.1002/(SICI)1521-3773(19990601)38:11<1632::AID-ANIE1632>3.0.CO

[10]

2-O

← 1 2 →