Dimeric 2,2-dimethyl-2-silabut-3-enyldiphenylphosphinecopper(I) bromide: a chelating olefinic-phosphine copper(I) complex

被引：9

作者：

Alyea, EC

Meehan, PR

Ferguson, G

Kannan, S

机构：

[1] Dept. of Chemistry and Biochemistry, University of Guelph, Guelph

来源：

POLYHEDRON | 1997年 / 16卷 / 19期

基金：

加拿大自然科学与工程研究理事会;

关键词：

mixed-donor ligand; phosphorus-olefin donation; copper bromide; crystal structure;

D O I：

10.1016/S0277-5387(97)00105-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between CuBr2 and 2,2-dimethyl-2-silabut-3-enyldiphenylphosphine (L-1) in methanol produced the title complex 1; the single crystal X-ray crystal structure of 1 reveals a centrosymmetric dimeric bromo-bridged species, with the copper(I) atoms bound to both the olefin and phosphorus donor sites on the ligands. (C) 1997 Elsevier Science Ltd.

引用

收藏

页码：3479 / 3481

页数：3

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