Selective binding of very hydrophilic H2PO4- anion by a hydrogen-bonding receptor adsorbed at the 1,2-dichloroethane-water interface

被引：30

作者：

Shigemori, K ^{[1
]}

Nishizawa, S ^{[1
]}

Yokobori, T ^{[1
]}

Shioya, T ^{[1
]}

Teramae, N ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan

来源：

NEW JOURNAL OF CHEMISTRY | 2002年 / 26卷 / 09期

关键词：

D O I：

10.1039/b203881a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A thiourea-functionalized benzo-15-crown-5 (TU-B15C5), adsorbed at the 1,2-dichloroethane water interface, can bind H2PO4- selectively over hydrophobic anions (H2PO4- > Cl-, ClO4-, Br-, CH3COO-) via the formation of hydrogen bonds.

引用

页码：1102 / 1104

页数：3

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