Studies of the N(D-2)+H-2 reaction on revised potential energy surfaces

被引：36

作者：

Kobayashi, H

Takayanagi, T

Tsunashima, S

机构：

[1] JAPAN ATOM ENERGY RES INST,TOKAI,IBARAKI 31911,JAPAN

[2] TOKYO INST TECHNOL,DEPT APPL PHYS,MEGURO KU,TOKYO 152,JAPAN

来源：

CHEMICAL PHYSICS LETTERS | 1997年 / 277卷 / 1-3期

关键词：

D O I：

10.1016/S0009-2614(97)00892-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The dynamics of the N(D-2) + H-2 reaction has been studied by quasiclassical trajectory methods and compared with the experimental results. Several potential energy surfaces were used. The product vibrational distribution was affected by the modification of the entrance channel barrier. Neither the product vibrational nor rotational distribution was affected by the modification of the deep well, which corresponds to NH2. The product rotational distribution was found to be mainly affected by the topology of potential energy surface at the exit channel region. (C) 1997 Elsevier Science B.V.

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页码：20 / 26

页数：7

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