Solid oxide fuel cells operating without using an anode material

被引：21

作者：

Hirabayashi, D

Tomita, A

Brito, ME

Hibino, T ^{[1
]}

Harada, U

Nagao, M

Sano, M

机构：

[1] Natl Inst Adv Ind Sci & Technol, Nagoya, Aichi 4638560, Japan

[2] Nagoya Univ, Grad Sch Environm Studies, Nagoya, Aichi 4660804, Japan

来源：

SOLID STATE IONICS | 2004年 / 168卷 / 1-2期

关键词：

solid oxide fuel cells BaCe(0.76)Y(0.20)Pr(0.04)O(3-x); anode material;

D O I：

10.1016/j.ssi.2004.01.024

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We proposed a new type of solid oxide fuel cell (SOFC) operating without using an anode material, where the anode was spontaneously formed by reduction of the electrolyte surface under reducing gas conditions. A BaCe(0.76)Y(0.20)Pr(0.04)O(3 - x) electrolyte most successfully met this criterion. This material showed high mixed protonic-electronic conduction, whereas the open circuit voltage (OCV) of the cell was slightly lower than the theoretical value. The resulting SOFC exhibited reasonable fuel cell performances together with a good stability to thermal and redox cyclings and high resistance to carbon deposition up to 800 degreesC for dry methane, ethane, and propane. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：23 / 29

页数：7

共 21 条

[1] PEROVSKITE SOLID ELECTROLYTES - STRUCTURE, TRANSPORT-PROPERTIES AND FUEL-CELL APPLICATIONS [J].