Tetraethynylethene molecular scaffolding: Nonlinear optical, redox, and amphiphilic properties of donor functionalized polytriacetylene and expanded radialenes

被引:52
作者
Schreiber, M
Tykwinski, RR
Diederich, F
Spreiter, R
Gubler, U
Bosshard, C
Poberaj, I
Gunter, P
Boudon, C
Gisselbrecht, JP
Gross, M
Jonas, U
Ringsdorf, H
机构
[1] ETH ZURICH,ORGAN CHEM LAB,CH-8092 ZURICH,SWITZERLAND
[2] ETH HONGGERBERG,INST QUANTENELEKT,LAB NICHTLINEARE OPTIK,CH-8092 ZURICH,SWITZERLAND
[3] UNIV STRASBOURG 1,FAC CHIM,URA CNRS 405,LAB ELECTROCHIM & CHIM PHYS CORPS SOLIDE,F-67008 STRASBOURG,FRANCE
[4] UNIV MAINZ,INST ORGAN CHEM,D-55099 MAINZ,GERMANY
关键词
D O I
10.1002/adma.19970090412
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Communication: Polymers,vith polytriacetylene (PTA) backbone (see the Figure), and also expanded radialenes (a new class of macrocycles with large conjugated all-carbon cores), are of interest because of their intrinsic two-dimensional pi-electron conjugated pathways. The synthesis, electrochemical characteristics, and linear and nonlinear optical properties of donor-functionalized polytriacetylene and donor endcapped expanded radialenes are reported and discussed.
引用
收藏
页码:339 / &
页数:6
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