Visualization of gas flow and diffusion in porous media

被引:44
作者
Kaiser, LG [1 ]
Meersmann, T
Logan, JW
Pines, A
机构
[1] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
[2] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
关键词
D O I
10.1073/pnas.050012497
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The transport of gases in porous materials is a crucial component of many important processes in science and technology. In the present work, we demonstrate how magnetic resonance microscopy with continuous flow laser-polarized noble gases makes it possible to "light up" and thereby visualize, with unprecedented sensitivity and resolution, the dynamics of gases in samples of silica aerogels and zeolite molecular sieve particles. The "polarization-weighted" images of gas transport in aerogel fragments are correlated to the diffusion coefficient of xenon obtained from NMR pulsed-field gradient experiments. The technique provides a unique means of studying the combined effects of flow and diffusion in systems with macroscopic dimensions and microscopic internal pore structure.
引用
收藏
页码:2414 / 2418
页数:5
相关论文
共 20 条
[1]  
ALBERT MS, 1994, NATURE, V370, P199, DOI 10.1038/370199a0
[2]   XE-129 NMR AS A PROBE FOR THE STUDY OF MICROPOROUS SOLIDS - A CRITICAL-REVIEW [J].
BARRIE, PJ ;
KLINOWSKI, J .
PROGRESS IN NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY, 1992, 24 (pt 2) :91-108
[3]  
Bear J., 1990, DYNAMICS FLUIDS PORO
[4]   Gas flow MRI using circulating laser-polarized 129Xe [J].
Brunner, E ;
Haake, M ;
Kaiser, L ;
Pines, A ;
Reimer, JA .
JOURNAL OF MAGNETIC RESONANCE, 1999, 138 (01) :155-159
[5]  
Callaghan P.T., 1991, Principles of nuclear magnetic resonance microscopy, V1st
[6]   MR microscopy of lung airways with hyperpolarized 3He [J].
Chen, XJ ;
Chawla, MS ;
Hedlund, LW ;
Möller, HE ;
MacFall, JR ;
Johnson, GA .
MAGNETIC RESONANCE IN MEDICINE, 1998, 39 (01) :79-84
[7]   High-volume production of laser-polarized Xe-129 [J].
Driehuys, B ;
Cates, GD ;
Miron, E ;
Sauer, K ;
Walter, DK ;
Happer, W .
APPLIED PHYSICS LETTERS, 1996, 69 (12) :1668-1670
[8]   MOTIONS AND RELAXATIONS OF CONFINED LIQUIDS [J].
GRANICK, S .
SCIENCE, 1991, 253 (5026) :1374-1379
[9]   Pore-structure determinations of silica aerogels by 129Xe NMR spectroscopy and imaging [J].
Gregory, DM ;
Gerald, RE ;
Botto, RE .
JOURNAL OF MAGNETIC RESONANCE, 1998, 131 (02) :327-335
[10]   POLARIZATION OF THE NUCLEAR SPINS OF NOBLE-GAS ATOMS BY SPIN EXCHANGE WITH OPTICALLY PUMPED ALKALI-METAL ATOMS [J].
HAPPER, W ;
MIRON, E ;
SCHAEFER, S ;
SCHREIBER, D ;
VANWIJNGAARDEN, WA ;
ZENG, X .
PHYSICAL REVIEW A, 1984, 29 (06) :3092-3110